Unable to Duplicate MicroSD for Booting OrangePi Zero3

Now I’m finally clear, this is NOT a bad hardware problem. Happened with another card of the same brand as the original one: both are SanDisk Extreme Pro 64GB.

After issuing the error message given in the original post the device reboots - and ends up in the same error (boot loop)
What exactly could be the reason for this behaviour?

Where in the boot process is that /dev/mtdblock4 mentioned? What is the device referring to?